各位前辈,我在研读一篇文献时遇到了一个没见过的概念,kinetical deblockage[size=13.7143px] 。其在原文中语境为 More attraction implies more exergonic stabilization of the corresponding transition state, e.g., a kinetical deblockage to accumulate the S-enantiomer through lowering the position of the first-order saddle-point on the potential energy surface