标题: NRR文献中的HER反应抑制，怎么做呢？ [打印本页] 作者Author: zzm925427892 时间: 2019-9-18 15:25 标题: NRR文献中的HER反应抑制，怎么做呢？ NRR中，如何表明HER反应被抑制了呢？
文献中，
As shown in Figure 6a, on W@C3N4 and Pt@C3N4, as H
strongly interacts with the W and Pt atoms, the HER process
is hindered by the Heyrovskey step (H* + H+ + e− → H2),
the free energy barriers (0.68 and 0.78 eV, respectively) are
larger than the PDS barriers for NRR on these two SACs
(0.35 and 0.64 eV). Thus, W@C3N4 and Pt@C3N4 exhibit high
suppressing effect on HER during the NRR process.